贵州某地玄武岩型氧化铜矿选矿试验研究     

狄永宁  余红林  王莉 《贵州地质》2009,26(1)

对贵州某地的玄武岩型氧化铜矿进行了可选性试验研究.对氧化矿采用的硫化浮选方法经试验不适合本矿,故采用离析浮选.采用离析、一次粗选的试验指标为:铜精矿品位26.70%,铜回收率84.36%.  相似文献   

纳米TiO2分离富集ICP-MS法测定河口环境样品中重金属研究     

黄霄红  卢豪良 《亚热带资源与环境学报》2013,(2):35-40

建立了以纳米二氧化钛（TiO2）作为吸附剂填充微柱,电感耦合等离子体质谱（ICP-MS）法测试Cu^2＋,Cd^2＋,Pb^2＋和Ni^2＋离子的分析方法．考察了不同pH值、洗脱液浓度、样品流速、体积和外源干扰离子的影响,实验结果表明在pH值8～10范围内待测离子可被TiO2定量吸附,2．0molL^-1HNO3可将吸附在微柱上的待测物完全洗脱,优化条件下本方法对溶液中Cu^2＋,Cd^2＋,Ph^2＋和M^2＋离子检出限分别为：0．02,0．01,0．01,0．02μgL～,相对标准偏差小于2％（n=7）,富集系数50倍．对水系沉积物标准物质（GBW07310）的测定值与标准值相一致,方法具有简便、快速,灵敏度高,重现性好的优点,可满足河口水体与沉积物样品中痕量金属元素定量分析的要求．  相似文献   

Preparation of Nano‐Lepidocrocite and an Investigation of Its Ability to Remove a Metal Complex Dye     

Mohsen Sheydaei  Soheil Aber 《洁净——土壤、空气、水》2013,41(9):890-898

Lepidocrocite (γ‐FeOOH) nanoparticles were synthesized from iron(II) sulfate solution and characterized using X‐ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform‐IR (FT‐IR), nitrogen adsorption, and point of zero charge pH (pH_PZC) analyses. TEM, XRD, and FT‐IR analyses proved the synthesis of nano‐lepidocrocite. Surface area and pH_PZC of the synthesized lepidocrocite were 68.1 m² g^?1 and 4.8, respectively. Utilization of the synthesized lepidocrocite in the adsorption of Lanacron brown S‐GL (LBS‐GL) from aqueous solutions was investigated, and the effect of lepidocrocite dosage, pH, temperature, and contact time on this process were optimized and modeled using response surface methodology approach. The lepidocrocite dosage of 0.015 g, pH 3.5, temperature of 38°C, and contact time of 100 min were determined as optimum adsorption conditions. Isotherm and kinetics of the adsorption process were analyzed at the optimum conditions. The equilibrium data were fitted well to the Langmuir isotherm model. The maximum monolayer adsorption capacity was 528.21 mg g^?1. The adsorption process was described by the pseudo‐second‐order kinetic model. Furthermore, the effect of pH on the desorption of LBS‐GL was investigated. High LBS‐GL desorption efficiency was achieved at a high pH value.  相似文献   

Possible link between new coronavirus variants and atmospheric lightning and seawater intrusion          下载免费PDF全文

Jianping Huang  Yingjie Zhao  Danfeng Wang 《大气和海洋科学快报》2022,15(1):100135

自新型冠状病毒肺炎暴发一年多以来,已经对全球产生深远影响.新型冠状病毒肺炎变异毒株的出现使当前疫情发展充满了不确定性.从这方面出发,我们讨论病毒变异与大气因素之间的联系.根据固氮过程和硝酸盐在人体中的转化过程,我们提出了新型冠状病毒肺炎变异毒株的出现或许和闪电以及海水入侵有联系.我们的研究对新型冠状病毒肺炎变异毒株可能的产生原因提供新的观点.  相似文献   

陈家岭钒矿选矿工艺试验     

李麟  尹进喜  冯艳华 《陕西地质》2012,30(1):82-88

采用钙法氧化焙烧——酸浸的方法从钒矿石中浸出钒,克服了钠化焙烧过程中产生的H2S、Cl2,实验了矿石物料粒度、氧化钙添加量、焙烧温度、焙烧时间、漫出温度、浸出时间、酸的浓度、浸出液固比对浸出率的影响,获得了88％的浸出率。实验表明,焙烧温度、酸的浓度、浸出温度、浸出时间、液固比是影响钒浸出率的重要因素。  相似文献   

氧化铬对铝型材厂碱蚀渣制备铝方柱石材料结构的影响     

罗旭东  曲殿利  张国栋  刘海啸  吕楠 《矿物学报》2012,32(1):146-150

利用铝型材厂碱蚀渣为主要原料,采用二步煅烧工艺制备铝方柱石材料。探索二次煅烧温度对铝型材厂碱蚀渣制备铝方柱石材料相组成、结晶度、微观结构的影响,进而研究氧化铬对铝方柱石材料相组成、微观结构的影响。采用同步热分析、X射线衍射、扫描电镜及相关分析软件表征制备的铝方柱石材料的相组成和显微结构。结果表明：铝型材厂碱蚀渣中有大量可烧失成分,物料需要进行致密化处理,再经过1500℃煅烧后的铝方柱石材料结构中具有明显的铝方柱石条柱状结构,结晶度增大,铝方柱石相对含量达到91%。随着氧化铬加入量增加,结构中的铝铬酸钙相增加。当氧化铬加入量为2%时,试样中结晶相的结晶度最高,形成条柱状铝方柱石相与立方状铝铬酸钙相共存的结构。当氧化铬加入量4%时,试样中铝方柱石相几乎消失,结晶度降低。  相似文献   

Petrogenesis of the Piqiang mafic-ultramafic layered intrusion and associated Fe-Ti-V oxide deposit in Tarim Large Igneous Province,NW China     

《International Geology Review》2012,54(18):2249-2275

ABSTRACT

The Piqiang intrusion is one of the two important ma?c-ultrama?c layered intrusions that host giant Fe-Ti-V oxide deposits in the Permian Tarim Large Igneous Province, NW China. The intrusion mainly consists of gabbro, anorthosite and minor plagioclase-bearing clinopyroxenite in the marginal zone. Disseminated to massive Fe-Ti oxide ores occur as layers and lenses within the gabbro. SHRIMP zircon U-Pb results from both a gabbro from the Piqiang intrusion and a granite from the surrounding granitic dyke yield ages of ~270 Ma. Geochemically, the Piqiang silicate rocks are enriched in light rare earth elements (LREE) and large ion lithophile elements (LILE), moderately depleted in high ?eld strength elements (HFSE), and have a limited range of Sr-Nd-Hf isotopic compositions. The similar mineralogy, mineral compositions, and trace element characteristics of the layered units suggest that all the rocks are co-magmatic. The parental magma is Fe-Ti-rich and is akin to the most primitive diabasic dyke which is associated with the Piqiang intrusion. Partial melting of the Tarim mantle plume with involvement of a subduction-metasomatized lithospheric mantle source best explains the geochemistry and petrogenesis of the parental magmas of the Piqiang intrusion. We propose that the lithospheric mantle source may have been metasomatized by subduction-related materials and the metasomatic enrichment of this source region which may be correlated with oceanic sediment recycling during southward subduction of the South Tianshan oceanic slab during the Early-Middle Paleozoic. Crystal settling and mechanical sorting is the predominant process responsible for the formation of the massive Fe-Ti oxide ores in the Piqiang intrusion. Central to ore formation is a combination of the protracted differentiation history of a Fe-Ti-enriched parental magma and the later addition of external H₂O from the country rocks to the slowly cooling magma chamber.  相似文献   

铁锰氧化物对苯酚氧化降解的实验研究     

文丽敏  张骏 《西安地质学院学报》2011,(2):191-195

为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究。土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿。结果表明：苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的升高而迅速下降;可用零级反应动力学方程拟合铁氧化物还原溶解反应,针铁矿溶解反应的强度与介质的pH值呈负相关关系;天然针铁矿对酚类污染物的氧化降解能力明显高于合成针铁矿,pH值对天然针铁矿溶解反应影响较大;可用一级指数衰减方程拟合锰氧化物还原溶解反应,锰氧化物溶解反应的强度与介质的pH值呈指数衰减关系;pH值对软锰矿还原溶解反应的影响大于对土壤中氧化锰的影响,pH值越小,影响越显著;对比pH值对铁和锰还原作用的影响发现,在pH=6.5时,锰氧化物仍有较强的氧化性能。  相似文献   

铁锰氧化物对苯酚氧化降解的实验研究   总被引：1，自引：0，他引：1  

文丽敏  张骏 《地球科学与环境学报》2011,33(2):191-195

为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究.土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿.结果表明:苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的...  相似文献   

活性MgO定量分析标准方法的比较研究          下载免费PDF全文

董金美  余红发  李颖  乔宏霞  王梅娟 《盐湖研究》2011,19(2):29-33

用WB和JC标准水合法测定轻烧MgO粉的活性MgO含量,对测定结果进行方差和误差分析,并研究了水化时间对测定结果的影响。结果表明,两种方法存在显著性差异,WB和JC水合法的平均相对误差分别为1.31%和-19.85%,WB水合法精密度远高于JC水合法。以WB水合法为基准,JC水合法的平均相对误差大于-20%,远远超过行业标准中规定的±3%。因此,对于镁水泥原料MgO中活性含量的定量分析,不能采用JC方法,必须采用WB方法。此外,发现水化3 h已经接近活性氧化镁的水化平衡,为修订WB标准方法提供了参考依据。  相似文献